Mahapatra, Susanta ; Koppel, Horst (1998) Quantum mechanical study of optical emission spectra of Rydberg-excited H3 and its isotopomers Physical Review Letters, 81 (15). pp. 3116-3119. ISSN 0031-9007
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Official URL: https://journals.aps.org/prl/abstract/10.1103/Phys...
Related URL: http://dx.doi.org/10.1103/PhysRevLett.81.3116
Abstract
Optical emission spectra of Rydberg-excited H3, D3, H2D, and D2H, in the range 200–400 nm, are investigated theoretically and compared with the experimental findings of Bruckmeier et al. [Phys. Rev. Lett. 72, 2550 (1994)]. The time-dependent wave packet method combined with the vibronic coupling theory for ( E×ε) Jahn-Teller systems is utilized in order to calculate the corresponding Franck-Condon emission profiles from the upper n=3 electronic state to the degenerate (2p)1E′ ground electronic manifold of those species. We obtain bimodal spectra with two maxima 9600cm-1 apart in good agreement with the experimental result.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Physical Society. |
ID Code: | 103410 |
Deposited On: | 01 Feb 2018 12:31 |
Last Modified: | 01 Feb 2018 12:31 |
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