Flexibility of the Cu(110)–O structure in the presence of pyridine

Carley, A. F. ; Davies, P. R. ; Jones, R. V. ; Kulkarni, G. U. ; Roberts, M. W. (1999) Flexibility of the Cu(110)–O structure in the presence of pyridine Chemical Communications (8). pp. 687-688. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1999...

Related URL: http://dx.doi.org/10.1039/A901221D

Abstract

The presence of pyridine is shown by STM to have a profound effect on the structure of a Cu(110)–O surface; the spacing within the 〈100〉 directed Cu–O chains is unchanged at 3.6 Å but there is an increase in the spacing between the chains from 5.1 to 7.7 Å; the flexibility of the Cu(110)–O structure is emphasised by the observation that the change in structure is reversible when the pyridine is thermally desorbed.

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