Low-temperature nonoxidative activation of methane over H-Galloaluminosilicate (MFI) zeolite

Choudhary, Vasant R. ; Kinage, Anil K. ; Choudhary, Tushar V. (1997) Low-temperature nonoxidative activation of methane over H-Galloaluminosilicate (MFI) zeolite Science, 275 (5304). pp. 1286-1288. ISSN 0036-8075

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Official URL: http://www.sciencemag.org/cgi/content/abstract/275...

Related URL: http://dx.doi.org/10.1126/science.275.5304.1286

Abstract

Conversion of methane to higher hydrocarbons by its low-temperature activation without forming undesirable carbon oxides is of great scientific and practical importance. Methane can be highly activated, yielding high rates of conversion to higher hydrocarbons and aromatics (10 to 45 percent) at low temperatures (400° to 600°C), by its reaction over H-galloaluminosilicate ZSM-5 type (MFI) zeolite in the presence of alkenes or higher alkanes. The methane activation results from its hydrogen-transfer reaction with alkenes.

Item Type:Article
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ID Code:10308
Deposited On:04 Nov 2010 06:04
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