Krishnamurthy, M. ; Bierbaum, Veronica M. ; Leone, Stephen R. (1997) Vibrational state dependence of the N2 + (v = 0–3) + HCl reaction at thermal energies Chemical Physics Letters, 281 (1-3). pp. 49-56. ISSN 0009-2614
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0009-2614(97)01221-9
Abstract
N2 + (v = 0–3) + HCl reaction rate constant is studied at thermal energies. The rate constants for v = 0, 1, 2 and 3 are 5.3(±1.6)×10−10, 8.3(±2.5)×10−10, 7.9(±2.4)×10−10 and 8.0(±2.4)×10−10 cm3 molecule−1 s−1, respectively, showing little or no dependence on vibrational excitation. Vibrational deactivation of the N2 + is at most 20% of the total removal rate. The branching ratio for the charge transfer channel to the hydrogen transfer channel is also not altered significantly by N2 + vibrational excitation.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 102679 |
Deposited On: | 02 Feb 2018 04:37 |
Last Modified: | 02 Feb 2018 04:37 |
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