Solution based rapid synthesis of AgCuO2 at room temperature

Padmavathy, Nagarajan ; Vijayaraghavan, Rajagopalan ; Kulkarni, Giridhar U. (2014) Solution based rapid synthesis of AgCuO2 at room temperature RSC Advances, 4 (107). pp. 62746-62750. ISSN 2046-2069

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...

Related URL: http://dx.doi.org/10.1039/C4RA11853G

Abstract

We report a single step synthesis of AgCuO2 within minutes resulting in a polycrystalline, single phase product crystallizing in a monoclinic system. Chemical composition analysis has confirmed the stoichiometry of the product with oxygen in slight excess (∼0.1). Growth of this oxide involved cuboidal nanoparticles in the initial stages and needle-like microstructures in the final one, as shown by scanning electron microscopy. The novelty of the method lies in the stabilization of Cu in the 3+ state under ambient conditions in a rapid aqueous process.

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Deposited On:04 Mar 2017 16:46
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