Singh, Rajiv K. ; Kumar, Jitendra ; Singh, Ramadhar ; Kant, Rama ; Rastogi, R. C. ; Chand, Suresh ; Kumar, Vikram (2006) Structure–conductivity correlation in ferric chloride-doped poly(3-hexylthiophene) New Journal of Physics, 8 . Article ID 112, 21 pages. ISSN 1367-2630
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Official URL: http://iopscience.iop.org/article/10.1088/1367-263...
Related URL: http://dx.doi.org/10.1088/1367-2630/8/7/112
Abstract
Poly(3-hexylthiophene) (P3HT) matrix has been chemically doped (redox doping) by ferric chloride (FeCl3) with different molar concentrations to get P3HT–FeCl3 charge-transfer complexes. The effect of redox doping on photo-physical, structural, and morphological properties and dc electrical conductivity of P3HT matrices has been examined. The dc conductivity has been measured on films of pristine P3HT and P3HT–FeCl3 charge-transfer complexes in the temperature range 6–300 K. Analysis of dc conductivity data reveals that in the temperature range 40–300 K, the dc conductivity is predominantly governed by Mott's 3-dimensional variable range hopping (3D-VRH); however, below 40 K tunnelling seems to dominate. A slight deviation from 3D-VRH to 1D-VRH is observed with an increase in doping level or precisely with an increase in the extent of P3HT–FeCl3 charge-transfer complexes. We attribute this deviation to the induced expansion in crystallographic lattices as revealed by x-ray diffraction data and formation of discrete conducting domains as observed by atomic force microscope imaging.
Item Type: | Article |
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Source: | Copyright of this article belongs to Institute of Physics. |
ID Code: | 102587 |
Deposited On: | 14 Jun 2017 18:06 |
Last Modified: | 14 Jun 2017 18:07 |
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