Nanostructured Cu and Cu@Cu2O core shell catalysts for hydrogen generation from ammonia–borane

Kalidindi, Suresh Babu ; Sanyal, Udishnu ; Jagirdar, Balaji R. (2008) Nanostructured Cu and Cu@Cu2O core shell catalysts for hydrogen generation from ammonia–borane Physical Chemistry Chemical Physics, 10 (38). pp. 5870-5874. ISSN 1463-9076

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2008...

Related URL: http://dx.doi.org/10.1039/B805726E

Abstract

Copper nanoparticles have been prepared by the solvated metal atom dispersion (SMAD) method. Oxidation of the SMAD prepared copper colloids resulted in Cu@Cu2O core shell structures (7.7 ± 1.8 nm) or Cu2O nanoparticles depending on the reaction conditions. The nano Cu, Cu@Cu2O core shell, and Cu2O particles were found to be catalytically active for the generation of hydrogen from ammonia–borane either viahydrolysis or methanolysis reaction.

Item Type:Article
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