Lakshminarayanan, P. S. ; Ravikumar, I. ; Suresh, E. ; Ghosh, Pradyut (2007) Encapsulation of halides within the cavity of a pentafluorophenyl-substituted tripodal amine receptor Inorganic Chemistry, 46 (12). pp. 4769-4771. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic062380g
Related URL: http://dx.doi.org/10.1021/ic062380g
Abstract
Pentafluorophenyl-substituted tripodal amine L, tris[[(2,3,4,5,6-pentafluorobenzyl)amino]ethyl]amine, is becoming a potential receptor for encapsulation of Cl- and Br- within the pseudo-C3-symmetric tris(2-aminoethyl)amine (L1) cavity upon protonation of the secondary amines. 1H NMR titration results indicate that [H3L]3+ binds with Cl- and Br- strongly compared to the [H3L2]3+ receptor, where L2 is N,N‘,N‘ ‘-tris[(2-benzylamino)ethyl]amine.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 102087 |
| Deposited On: | 23 Jan 2017 10:03 |
| Last Modified: | 23 Jan 2017 10:03 |
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