An efficient synthesis of anti-(1R)-(+)-camphorquinone 3-oxime

Roy, Susmita ; Chakraborti, Asit K. (1998) An efficient synthesis of anti-(1R)-(+)-camphorquinone 3-oxime Tetrahedron Letters, 39 (35). pp. 6355-6356. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(98)01307-0

Abstract

Nitrosation of camphor with iso-amylnitrite in presence of base leads to the title compound in high yields. Excellent stereoselectivity is observed leading to preferential formation of the anti-isomer.

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