A mild and chemoselective method for deprotection of aryl acetates and benzoates under non-hydrolytic condition

Chakraborti, Asit K. ; Sharma, Lalima ; Sharma, Upasana (2001) A mild and chemoselective method for deprotection of aryl acetates and benzoates under non-hydrolytic condition Tetrahedron, 57 (45). pp. 9343-9346. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)00922-X

Abstract

Chemoselective deprotection of aryl acetates and benzoates can be achieved under non-hydrolytic condition by treatment with K2CO3 in N-methyl-2-pyrrolidone (NMP) at 100°C. Selective cleavage of aryl acetates and benzoates take place in the presence of alkyl carboxylates during intramolecular competitions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Deprotection; Arylacetate; Benzoate; Non-Hydrolytic Condition
ID Code:101054
Deposited On:19 Jan 2017 07:10
Last Modified:19 Jan 2017 07:12

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