Surface complexation reaction for phase transfer of hydrophobic quantum dot from nonpolar to polar medium

Abstract

Chemical reaction between oleate-capped Zn_xCd_1–xS quantum dots (Qdots) and 8-hydroxyquinoline (HQ) led to formation of a surface complex, which was accompanied by transfer of hydrophobic Qdots from nonpolar (hexane) to polar (water) medium with high efficiency. The stability of the complex on the surface was achieved via involvement of dangling sulfide bonds. Moreover, the transferred hydrophilic Qdots-herein called as quantum dot complex (QDC)-exhibited new and superior optical properties in comparison to bare inorganic complexes with retention of the dimension and core structure of the Qdots. Finally, the new and superior optical properties of water-soluble QDC make them potentially useful for biological-in addition to light emitting device (LED)-applications.