Chakraborti, Asit K. ; Rudrawar, Santosh ; Kondaskar, Atul (2004) An efficient synthesis of 2-amino alcohols by silica gel catalysed opening of epoxide rings by amines Organic and Biomolecular Chemistry, 2 (9). pp. 1277-1280. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2004...
Related URL: http://dx.doi.org/10.1039/b400588k
Abstract
Silica gel (60–120 mesh) efficiently catalyses the opening of epoxides by amines at rt under solvent-free conditions. Non-styrenoidal unsymmetrical alkene oxides undergo selective nucleophilic attack at the sterically less hindered carbon by aniline. A complementary regioselectivity is exhibited by aromatic and aliphatic amines during the reaction with styrene oxide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 100649 |
| Deposited On: | 18 Jan 2017 11:27 |
| Last Modified: | 18 Jan 2017 11:27 |
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