Probing molecular self-assembly by hyper-Rayleigh scattering in solution

Ray, Paresh Chandra ; Das, Puspendu Kumar (1997) Probing molecular self-assembly by hyper-Rayleigh scattering in solution Chemical Physics Letters, 281 (4-6). pp. 243-246. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00092...

Related URL: http://dx.doi.org/10.1016/S0009-2614(97)00975-5

Abstract

The formation of a noncovalent self-assembly of melamine and cyanuric acid is probed by the hyper-Rayleigh scattering technique. It is shown that the intensity of the scattered second harmonic light in solution increases significantly as the 1:1 complex of melamine and cyanuric acid is formed. Both the formation and destabilization of the hydrogen-bonded complex between these two molecules can easily be monitored by this technique.

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