Seth, Kapileswar ; Roy, Sudipta Raha ; Pipaliya, Bhavin V. ; Chakraborti, Asit K. (2013) Synergistic dual activation catalysis by palladium nanoparticles for epoxide ring opening with phenols Chemical Communications, 49 (52). pp. 5886-5888. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2013...
Related URL: http://dx.doi.org/10.1039/C3CC42507J
Abstract
Synergistic dual activation catalysis has been devised for epoxide phenolysis wherein palladium nanoparticles induce electrophilic activation via coordination with the epoxide oxygen followed by nucleophilic activation through anion–π;interaction with the aromatic ring of the phenol, and water (reaction medium) also renders assistance through ‘epoxide–phenol’ dual activation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 100267 |
| Deposited On: | 18 Jan 2017 12:35 |
| Last Modified: | 18 Jan 2017 12:35 |
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