Bera, Jitendra K. ; Fanwick, Phillip E. ; Walton, Richard A. (2001) Reaction of Re2(μ-O2CCH3)4Cl2 with bis(dicyclohexylphosphino)methane (dcpm): isolation of the mixed-valent complex O3ReReCl(η2-dcpm)2 containing an unsupported Re−Re bond Inorganic Chemistry, 40 (12). pp. 2914-2917. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/full/10.1021/ic0100471
Related URL: http://dx.doi.org/10.1021/ic0100471
Abstract
The reaction of Re2(μ-O2CCH3)4Cl2 with Cy2PCH2PCy2 (dcpm) affords a separable mixture of trans-ReOCl(η2-dcpm)2 (1) and trans-Re2(μ-O2CCH3)2Cl2(μ-dcpm)2 (2). Complex 1 is converted in the presence of O2 to the novel mixed-valent Re(VI)−Re(I) complex O3ReReCl(η2-dcpm)2 (3), which contains an unsupported Re−Re bond.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 100226 |
| Deposited On: | 27 Nov 2016 13:23 |
| Last Modified: | 27 Nov 2016 13:23 |
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