Opening of N-tosyl aziridines with nucleophiles catalyzed by phosphomolybdic acid supported on silica gel

Baskaran, Sundarababu ; Kishore Kumar, G. D. (2004) Opening of N-tosyl aziridines with nucleophiles catalyzed by phosphomolybdic acid supported on silica gel Synlett (10). pp. 1719-1722. ISSN 0936-5214

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Official URL: https://www.thieme-connect.de/DOI/DOI?10.1055/s-20...

Related URL: http://dx.doi.org/10.1055/s-2004-829574

Abstract

An environmentally benign H3PMO12O40-SiO2-catalyzed regioselective opening of activated aziridines with alcohols, azide, cyanide and bromide, at ambient temperature to afford the corresponding β-amino derivatives in good yields is described.

Item Type:Article
Source:Copyright of this article belongs to Thieme Publishing.
Keywords:Phosphomolybdic acid; Silica gel; Aziridines; Regioselectivity; Alcoholysis; β-Amino ether; β-Azido amine; β-Cyano amine; β-Bromo Amine
ID Code:100188
Deposited On:12 Feb 2018 12:22
Last Modified:12 Feb 2018 12:22

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