A rare unsupported iridium(II) dimer, [IrCl2(CO)2]2

Patra, Sanjib K. ; Rahaman, S. M. Wahidur ; Majumdar, Moumita ; Sinha, Arup ; Bera, Jitendra K. (2008) A rare unsupported iridium(II) dimer, [IrCl2(CO)2]2 Chemical Communications (22). pp. 2511-2513. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2008...

Related URL: http://dx.doi.org/10.1039/B803632B

Abstract

Oxidative additions of dichloromethanes to a diiridium(I) core, bridged by 2-ferrocenyl-1,8-naphthyridines (NP-Fc), provide an iridium(II) dimer, [IrCl2(CO)21-NP-Fc)]2, featuring an unsupported Ir–Ir single bond (2.7121(8) Å).

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