Concise enantioselective construction of a bridged azatricyclic framework via domino semipinacol–schmidt reaction

Puppala, Manohar ; Murali, Annamalai ; Baskaran, Sundarababu (2012) Concise enantioselective construction of a bridged azatricyclic framework via domino semipinacol–schmidt reaction Chemical Communications, 48 . pp. 5778-5780. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2012...

Related URL: http://dx.doi.org/10.1039/C2CC31906C

Abstract

A TiCl4-promoted domino semipinacol–Schmidt reaction of oxaspiropentane-azide provides an easy access to bridged azatricyclic ring systems, which possess the azaquaternary center, present in the immunosupressant FR901483 and platelet aggregation inhibitor daphlongeranine B.

Item Type:Article
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ID Code:100027
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