Patra, Sanjib K. ; Bera, Jitendra K. (2007) C−C bond forming reaction through aldol-type addition mediated by a [Ru2(CO)4]2+ core Organometallics, 26 (10). pp. 2598-2603. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/full/10.1021/om070139j
Related URL: http://dx.doi.org/10.1021/om070139j
Abstract
An aldol-like addition of acetone to 2-methyl-1,8-naphthyridine and 2,3-dimethyl-1,8-naphthyridine mediated by a [Ru2(CO)4]2+ core at room temperature affords the C−C-coupled compounds 2-methyl-1-(1,8-naphthyridin-2-yl)propan-2-ol (L1) and 2-methyl-1-(3-methyl-1,8-naphthyridin-2-yl)propan-2-ol (L2). A similar reaction with methyl ethyl ketone and 2-methyl-1,8-naphthyridine affords 2-methyl-1-(1,8-naphthyridin-2-yl)butan-2-ol (L3). The syntheses and structures of [Ru2(CO)4(L1)2][X]2 (2, X = BF4; 2a, X = OTf), [Ru2(CO)4(L2)2][BF4]2 (3), and [Ru2(CO)4(L3)2][BF4]2 (4) are reported here.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 99998 |
| Deposited On: | 27 Nov 2016 13:24 |
| Last Modified: | 27 Nov 2016 13:24 |
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