Smucker, Bradley W. ; Bacsa, John ; Bera, Jitendra K. ; Reinheimer, Eric W. (2015) Redox-active TTF carboxylate as an axial bridging ligand for dirhenium metal–metal bonded complexes Inorganica Chimica Acta, 425 . pp. 233-238. ISSN 0020-1693
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.ica.2014.10.002
Abstract
Tetrathiafulvalene monocarboxylate, [TTFCO2]−, was used as a carboxylate bridging ligand for three new dirhenium complexes. The acetate ligands of cis-Re2(dppm)2Cl2(OAc)2, trans-Re2(dppm)2Cl4(OAc), and cis-Re2Cl4(OAc)2 are displaced by TTFCO2H to form cis-Re2(dppm)2Cl2(TTFCO2)2 (1), trans-Re2(dppm)2Cl4(TTFCO2) (2), and cis-Re2Cl4(TTFCO2)2 (3), respectively. Depending on their respective solubility, the complexes were characterized via single crystal X-ray diffraction as well as electrochemical and spectroscopic properties.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Tetrathiafulvalene Monocarboxylate; Dirhenium Compounds; Redox Properties; X-ray Crystal Structures |
| ID Code: | 99962 |
| Deposited On: | 27 Nov 2016 13:28 |
| Last Modified: | 27 Nov 2016 13:28 |
Repository Staff Only: item control page
