Bulky, spherical, and fluorinated anion BArF induces 'on-water' activity of silver salt for the hydration of terminal alkynes

Saha, Sayantani ; Sarbajna, Abir ; Bera, Jitendra K. (2014) Bulky, spherical, and fluorinated anion BArF induces 'on-water' activity of silver salt for the hydration of terminal alkynes Tetrahedron Letters, 55 (8). pp. 1444-1447. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2014.01.045

Abstract

AgBArF displays remarkable 'on-water' activity for catalytic hydration of terminal alkynes although it is ineffective in common organic solvents. Liquid alkynes do not require additive or co-solvent whereas a small amount of ethyl acetate triggers quantitative conversions for solid alkynes.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Alkyne; Silver; Catalysis; Hydration; On-Water
ID Code:99917
Deposited On:27 Nov 2016 13:22
Last Modified:27 Nov 2016 13:22

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