Chain compounds based on transition metal backbones: new life for an old topic

Bera, Jitendra K. ; Dunbar, Kim R. (2002) Chain compounds based on transition metal backbones: new life for an old topic Angewandte Chemie International Edition, 41 (23). pp. 4453-4457. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...

Related URL: http://dx.doi.org/10.1002/1521-3773(20021202)41:23<4453::AID-ANIE4453>3.0.CO;2-1

Abstract

A new link in the chain: After a long period of inactivity, research into one-dimensional compounds based on linear arrays of transition metals is experiencing a renaissance. Recently, oligomeric and polymeric chains have been reported for a variety of transition metals. One such compound of a particularly exotic variety is depicted here, in which a {Pd4}2+ unit is surrounded by a “π-electron sheath” of conjugated polyene ligands.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Chain Structures; Conducting Materials; Metal–metal Interactions; Nanotechnology; Transition Metals
ID Code:99134
Deposited On:20 Oct 2015 09:13
Last Modified:20 Oct 2015 09:13

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