Semiclassical quantization of multidimensional systems

Ramaswamy, Ramakrishna ; Siders, P. ; Marcus, R. A. (1980) Semiclassical quantization of multidimensional systems The Journal of Chemical Physics, 73 . p. 5400. ISSN 0021-9606

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Low order classical perturbation theory is used to obtain semiclassical eigenvalues for a system of three anharmonically coupled oscillators. The results in the low energy region studied here agree well with the ’’exact’’ quantum values. The latter had been calculated by matrix diagonalization using a large basis set.

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