An unusual solvent effect in the cuprate displacement reaction of indolizidin-5-yl-methyl p-toluenesulfonate: stereoselective synthesis of indolizidine alkaloids

Reddy, Ganapati P. ; Sankar, Gomathi M. ; Baskaran, Sundarababu (2005) An unusual solvent effect in the cuprate displacement reaction of indolizidin-5-yl-methyl p-toluenesulfonate: stereoselective synthesis of indolizidine alkaloids Tetrahedron Letters, 46 (27). pp. 4559-4561. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.05.008

Abstract

An unusual solvent effect in the cuprate displacement reaction of indolizidin-5-yl-methyl p-toluenesulfonate with dialkyl cuprates, derived from an alkyllithium and Grignard reagents, during the synthesis of indolizidine alkaloids 167B and 209D is described.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Cuprate Displacement; Solvent Effect; Stereoselective; Indolizidine Alkaloids; Nucleophilic Substitution
ID Code:98553
Deposited On:19 Sep 2014 11:50
Last Modified:19 Sep 2014 11:50

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