Bose, Moumita ; Moula, Golam ; Sarkar, Sabyasachi (2014) A cyanide-bridged molybdenum bis(maleonitriledithiolate) square Inorganic Chemistry, 53 (1). pp. 6-8. ISSN 0020-1669
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/ic402160h
Related URL: http://dx.doi.org/10.1021/ic402160h
Abstract
[Et4N]2[MoIVO(mnt)2] (mnt = maleonitriledithiolate) reacts, as a synthon, with Me3SiCN under an acidic medium to produce the square complex [Et4N]4[Mo4(μ-CN)4(mnt)8] (1) in high yield. Complex 1 shows strong antiferromagnetic interactions between adjacent Mo atoms in the cluster. The presence of redox-active mnt as a capping ligand strongly influences the magnetic property of 1. The physicochemical properties of 1 have been rationalized by density functional theory level of calculations.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 98297 |
| Deposited On: | 14 May 2014 10:25 |
| Last Modified: | 14 May 2014 10:25 |
Repository Staff Only: item control page
