A cyanide-bridged molybdenum bis(maleonitriledithiolate) square

Bose, Moumita ; Moula, Golam ; Sarkar, Sabyasachi (2014) A cyanide-bridged molybdenum bis(maleonitriledithiolate) square Inorganic Chemistry, 53 (1). pp. 6-8. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic402160h

Related URL: http://dx.doi.org/10.1021/ic402160h


[Et4N]2[MoIVO(mnt)2] (mnt = maleonitriledithiolate) reacts, as a synthon, with Me3SiCN under an acidic medium to produce the square complex [Et4N]4[Mo4(μ-CN)4(mnt)8] (1) in high yield. Complex 1 shows strong antiferromagnetic interactions between adjacent Mo atoms in the cluster. The presence of redox-active mnt as a capping ligand strongly influences the magnetic property of 1. The physicochemical properties of 1 have been rationalized by density functional theory level of calculations.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:98297
Deposited On:14 May 2014 10:25
Last Modified:14 May 2014 10:25

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