Transcription and amplification of molecular chirality to oppositely biased supramolecular π helices

Ajayaghosh, Ayyappanpillai ; Varghese, Reji ; George, Subi Jacob ; Vijayakumar, Chakkooth (2006) Transcription and amplification of molecular chirality to oppositely biased supramolecular π helices Angewandte Chemie International Edition, 45 (7). pp. 1141-1144. ISSN 1433-7851

Full text not available from this repository.

Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.200503142

Abstract

Let's twist again: Transcription of molecular chirality from common stereogenic centers to amplified supramolecular chirality during the coassembly of gel-forming π-conjugated molecules by inverted helicity results in the formation of longitudinally fused M and P helices. This “sergeants and soldiers” approach to coassembly under stereomutation has been confirmed by CD and AFM techniques (see picture).

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Chirality; Gels; Helical Structures; Scanning Probe Microscopy; Self-Assembly
ID Code:96149
Deposited On:05 Dec 2012 11:59
Last Modified:05 Dec 2012 11:59

Repository Staff Only: item control page