Sharma, Krishna ; Darshane, Vishnu S. ; Manoharan, Periyakaruppan T. ; Bhaduri, S. (1992) Polyamino acids and cytochrome C anchored rhodium complexes Proceedings of the Indian Academy of Sciences - Chemical Sciences, 104 (5). pp. 535-542. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/104/1/535-5...
Related URL: http://dx.doi.org/10.1007/BF02843547
Abstract
Polyamino acids (amino acid = valine, alanine, lysine and arginine) and the protein cytochrome C (Cyt C) have been treated with [Rh(CO)2Cl]2 (1) to give polymersupportedcis-dicarbonyl species. The polymer-supported rhodium complexes, characterised on the basis of infrared and ESCA data, have been found to undergo reversible decarbonylation reaction. The Cyt C-supported rhodium complex acts as a hydrogenation catalyst of low to moderate activity. In the hydrogenation of 3-methyl cyclohexanone no stereoselectivity has been observed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Cytochrome C; Polyaminoacids; Infrared and ESCA Data; Hydrogenation Catalyst |
| ID Code: | 95710 |
| Deposited On: | 26 Dec 2012 07:05 |
| Last Modified: | 19 May 2016 08:17 |
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