An efficient synthesis of trihydroxy quinolizidine alkaloids using ring-closing metathesis

Dhavale, D. D. ; Jachak, Santosh M. ; Karche, Navnath P. ; Trombini, Claudio (2004) An efficient synthesis of trihydroxy quinolizidine alkaloids using ring-closing metathesis Synlett (9). pp. 1549-1552. ISSN 0936-5214

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2004-829538

Abstract

The sequential C- and N-allylation of D-glucose-derived nitrone 2 provides the required diene functionality with nitrogen linker that was used in ring-closing metathesis pathway in the synthesis of quinolizidine alkaloids 1a and 1b.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers Inc.
Keywords:Alkaloids; Azasugars; Carbohydrates; Glycosidase; Metathesis
ID Code:9570
Deposited On:02 Nov 2010 11:53
Last Modified:31 May 2011 11:59

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