Crystal and molecular structure of N-methylphenazinium bis(maleonitriledithiolato)gold(III), [NMP]+[Au(mnt)2]-

Kuppusamy, P. ; Venkatalakshmi, N. ; Manoharan, P. T. (1985) Crystal and molecular structure of N-methylphenazinium bis(maleonitriledithiolato)gold(III), [NMP]+[Au(mnt)2]- Journal of Crystallographic and Spectroscopic Research, 15 (6). pp. 629-641. ISSN 0277-8068

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Official URL: http://link.springer.com/article/10.1007%2FBF01164...

Related URL: http://dx.doi.org/10.1007/BF01164776

Abstract

The crystal and molecular structure of the title compound, C21H11N6S4Au, is reported. The crystals are triclinic:P¯1,Z=2,a=7.739(1),b=8.415(1),c=17.815(1) Å,a=101.31(1),β=86.20(1), γ=98.17(1)°. The structure was solved by the heavy-atom method, and refined by full-matrix least squares toR=0.046. Both the Au(mnt) 2 and NMP+ ions are planar, and form a kind of mixed stack alonga, with slightly alternating NMP+-Au(mnt)- 2 distances of 3.46(8) and 3.59(5) Å.

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ID Code:95694
Deposited On:20 Nov 2012 10:44
Last Modified:20 Nov 2012 10:44

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