Mössbauer spectra of cubic hexanitroferrates

Manoharan, P. T. ; Kaliraman, S. S. ; Jadhao, V. G. ; Singru, R. M. (1972) Mössbauer spectra of cubic hexanitroferrates Chemical Physics Letters, 13 (6). pp. 585-588. ISSN 0009-2614

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0009-2614(72)85019-X


The quadrupole splitting measured in the cubic hexanitroferrates has been explained in terms of a lower symmetry arising out of the hindered rotations of the nitro groups. The isomer shifts of these compounds indicate that π-back donation between the metal atom and nitro group is very weak.

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ID Code:95661
Deposited On:19 Nov 2012 10:38
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