Manoharan, P. T. ; Rogers, M. T. (1968) ESR Study of VOF53− Ion Journal of Chemical Physics, 49 (9). p. 3912. ISSN 0021-9606
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Official URL: http://jcp.aip.org/resource/1/jcpsa6/v49/i9/p3912_...
Related URL: http://dx.doi.org/10.1063/1.1670700
Abstract
Spin‐Hamiltonian parameters for the VOF53− ion were determined from solution, frozen glass, powder, and single‐crystal ESR spectra. The most important finding is the presence of superhyperfine splittings due to the equatorial and axial fluorine ligands; the strongest interaction is found to result from the in‐plane π bonding between the 3dxy orbital of vanadium and the 2py orbitals of fluorine. Bonding in the complex ion has been discussed in terms of LCAO MO theory.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Institute of Physics. |
| ID Code: | 95655 |
| Deposited On: | 19 Nov 2012 10:30 |
| Last Modified: | 19 Nov 2012 10:30 |
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