ESR Study of VOF53− Ion

Manoharan, P. T. ; Rogers, M. T. (1968) ESR Study of VOF53− Ion Journal of Chemical Physics, 49 (9). p. 3912. ISSN 0021-9606

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Spin‐Hamiltonian parameters for the VOF53− ion were determined from solution, frozen glass, powder, and single‐crystal ESR spectra. The most important finding is the presence of superhyperfine splittings due to the equatorial and axial fluorine ligands; the strongest interaction is found to result from the in‐plane π bonding between the 3dxy orbital of vanadium and the 2py orbitals of fluorine. Bonding in the complex ion has been discussed in terms of LCAO MO theory.

Item Type:Article
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ID Code:95655
Deposited On:19 Nov 2012 10:30
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