Sengupta, S. ; Chakravorty, A. (2006) Rhenium chemistry of pyridyldiazoles : oxorhenium(V) and imidorhenium(V) species Journal of the Indian Chemical Society, 83 (6). pp. 556-562. ISSN 0019-4522
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Official URL: http://www.indianchemsoc.org/jourindx.htm
Abstract
The first diazole complexes of rhenium have been isolated and characterized in the form of the oxo and imido species of general type [ReOCl3(L)] and [Re(NPh)Cl3(L)] where L is 2,5-bis(2-pyridyl)-1,3,4-oxadiazole or 2,5-bis(2-pyridyl)-l,3,4-thiadiazole. Structure determination has revealed meridional geometry, oxo/imido triple bonding and aromatic lattice interactions. The chelates display a relatively weak ligand field band in the visible region and a quasireversible ReVI/ReV cyclic voltammetric response.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Chemical Society. |
| ID Code: | 95335 |
| Deposited On: | 13 Nov 2012 12:10 |
| Last Modified: | 13 Nov 2012 12:10 |
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