A manganese tris quinone oximato pair revealing new structures and magnetic properties in MnIII,II chemistry

Basu, Partha ; Chakravorty, Animesh (1992) A manganese tris quinone oximato pair revealing new structures and magnetic properties in MnIII,II chemistry Journal of the Chemical Society, Chemical Communications (11). pp. 809-810. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1992...

Related URL: http://dx.doi.org/10.1039/C39920000809

Abstract

The synthesis and isomerism of the first tris-chelated low-spin MnIII(1a) and MnII(1b) pair of complexes [MnL3]0,–, of the 4-chloro-o-benzoquinone oxime ligand HL is described; MnL3 has strong preference for mer-geometry but mer- and fac-isomers coexist in solution as well as in the crystal lattice of the [Et4N]+ salt of [MnL3].

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