Redox in a ferroverdin analogue: recognition of isomeric co-ordination spheres by FeII and FeIII

Basu, Partha ; Pal, Samudranil ; Chakravorty, Animesh (1989) Redox in a ferroverdin analogue: recognition of isomeric co-ordination spheres by FeII and FeIII Journal of the Chemical Society, Chemical Communications, 15 . pp. 977-978. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1989...

Related URL: http://dx.doi.org/10.1039/C39890000977

Abstract

The N3O3 co-ordination sphere of (1b) and (1c) selectively stabilises low-spin FeII and FeIII in fac(2a) and mer(2b) geometries, respectively; mismatched combinations generated by rapid chemical/electrochemical electron transfer at low temperatures undergo spontaneous isomerisation at measurable rates to achieve equilibrium populations.

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