Oxygen insertion into the metal–carbon bond of cyclopalladated 2-(alkylsulphinyl)azobenzenes by peracids. High yield regiospecific aromatic hydroxylation

Sinha, Chitta R. ; Bandyopadhyay, Debkumar ; Chakravorty, Animesh (1988) Oxygen insertion into the metal–carbon bond of cyclopalladated 2-(alkylsulphinyl)azobenzenes by peracids. High yield regiospecific aromatic hydroxylation Journal of the Chemical Society, Chemical Communications (7). pp. 468-470. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1988...

Related URL: http://dx.doi.org/10.1039/C39880000468

Abstract

The title reaction occurs by an associative mechanism involving heterolytic O–O cleavage; the sequence azobenzene →(1)→(2)→ azophenol leading to overall regiospecific aromatic hydroxylation has been realised.

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