Aromatic hydroxylation: the direct oxidation of C–Pd into C–OPd

Mahapatra, Amiya K. ; Bandyopandhyay, Debkumar ; Bandyopadhyay, Pinaki ; Chakravorty, Animesh (1984) Aromatic hydroxylation: the direct oxidation of C–Pd into C–OPd Journal of the Chemical Society, Chemical Communications (15). pp. 999-1000. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1984...

Related URL: http://dx.doi.org/10.1039/C39840000999

Abstract

The C–Pd bond in cyclopalladated azobenzenes [(1) and (3)] is converted into the C–OPd function [(2) and (5)] in good yield by stoicheiometric reactions with m-chloroperbenzoic acid; in effect azobenzene is successively oxidised to 2-hydroxyazobenzene and 2,2′-hydroxyazobenzene.

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