Charge transfer spectra of some gold(III) complexes

Gangopadhayay, Arun Kumar ; Chakravorty, Animesh (1961) Charge transfer spectra of some gold(III) complexes Journal of Chemical Physics, 35 (6). p. 2206. ISSN 0021-9606

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Tetrahalo complexes of Au(III) show two intense bands in the ultraviolet. These are interpreted as charge‐transfer bands; the transfer is from halogen p to gold d orbitals. The two bands are associated with pσ→dx2—y2 and pπ→dx2—y2 transitions. The iodo complex undergoes spontaneous reduction; reason for this is discussed. The ethylenediamine complexes of Au(III) also exhibit interesting charge‐transfer phenomenon.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Physics.
ID Code:95223
Deposited On:25 Oct 2012 04:36
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