Charge transfer spectra of some gold(III) complexes

Gangopadhayay, Arun Kumar ; Chakravorty, Animesh (1961) Charge transfer spectra of some gold(III) complexes Journal of Chemical Physics, 35 (6). p. 2206. ISSN 0021-9606

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Official URL: http://jcp.aip.org/resource/1/jcpsa6/v35/i6/p2206_...

Related URL: http://dx.doi.org/10.1063/1.1732233

Abstract

Tetrahalo complexes of Au(III) show two intense bands in the ultraviolet. These are interpreted as charge‐transfer bands; the transfer is from halogen p to gold d orbitals. The two bands are associated with pσ→dx2—y2 and pπ→dx2—y2 transitions. The iodo complex undergoes spontaneous reduction; reason for this is discussed. The ethylenediamine complexes of Au(III) also exhibit interesting charge‐transfer phenomenon.

Item Type:Article
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