Media controlled photo-Favorskii type rearrangement of α-chloro acetophenones: synthesis of phenylacetic acids

Dhavale, Dilip D. ; Mali, Vasant P. ; Sudrik, Surendra G. ; Sonawane, Harikisan R. (1997) Media controlled photo-Favorskii type rearrangement of α-chloro acetophenones: synthesis of phenylacetic acids Tetrahedron, 53 (49). pp. 16789-16794. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4020(97)10081-3

Abstract

Photolysis of substituted α-chloro acetophenones has been studied in different solvent systems wherein 1,2-aryl migration is found to be media controlled. Effect of substituents on the migratory aptitude and a direct access to phenylacetic acids, in practical yields, has been described.

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