Collision broadening of C2H4O lines. II. broadened by quadrupolar molecules N2 and H2

Pandey, Prem Chand ; Srivastava, Shyam Lal (1973) Collision broadening of C2H4O lines. II. broadened by quadrupolar molecules N2 and H2 The Journal of Chemical Physics, 58 (4). 1630_1-1630_6. ISSN 0021-9606

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Official URL: http://jcp.aip.org/resource/1/jcpsa6/v58/i4/p1630_...

Related URL: http://dx.doi.org/10.1063/1.1679406

Abstract

A double modulation microwave spectrograph has been used to measure the linewidth parameters (Δν/p) of four rotational lines of C2H4O broadened by quadrupolar molecules N2 and H2. Linewidth parameters have been calculated theoretically using the Anderson‐Tsao‐Curnutte theory as well as the Murphy‐Boggs formulation taking the dipole‐quadrupole interaction into consideration. By fitting the calculated (Δν/p) to the measured (Δν/p), molecular quadrupole moments Θ of N2 and H2 have been obtained. Inadequacies in the theory have been pointed out.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Physics.
ID Code:94501
Deposited On:14 Sep 2012 12:21
Last Modified:14 Sep 2012 12:21

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