New Synthesis of dibenzo[b,f-1,4]oxazepine, dibenzo[b,f-1,4]thiazepine & dibenzo[6,e-1,4]diazepine derivatives

Nagarajan, K. ; Kulkarni, C. L. ; Venkateswarlu, A. (1968) New Synthesis of dibenzo[b,f-1,4]oxazepine, dibenzo[b,f-1,4]thiazepine & dibenzo[6,e-1,4]diazepine derivatives Indian Journal of Chemistry, 6 (4). pp. 225-226. ISSN 0019-5103

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Abstract

Beckmann rearrangement of xanthone oxime and thermal cyclization of the sodium salt of ,N-(2'-chloro-benzbyl)-2-hydroxyaniline yield 10,11- dihydro-11-oxo-dibenzo[b, f-1,4]oxazepine. Similar syntheses are reported for dibenzo [b, f-1,4]thiazepine and dibenzo[b,e-l, 4] diazepine derivatives.

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