Nafion-H catalyzed isomerization of glycidic to α-hydroxy-β,γ-unsaturated esters: application in the synthesis of a trifluoromethylated vinylic epoxide

Hachoumy, Mohammed ; Mathew, Thomas ; Tongco, Emily C. ; Vankar, Yashwant D. ; Surya Prakash, G. K. (1999) Nafion-H catalyzed isomerization of glycidic to α-hydroxy-β,γ-unsaturated esters: application in the synthesis of a trifluoromethylated vinylic epoxide Synlett, 1999 (3). pp. 363-365. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-1999-2611

Abstract

Facile Nafion-H catalyzed isomerization of glycidic esters to α-hydroxy-β,γ-unsaturated esters is reported. These compounds are useful synthetic intermediates. Application in the synthesis of a trifluoromethylated vinylic epoxide is demonstrated.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Nafion-H; Glycidic Esters; α-hydroxy-α,γ-unsaturated Esters; Trifluoromethyltrimethylsilane; Vinylic Epoxide
ID Code:93374
Deposited On:15 Jun 2012 13:28
Last Modified:15 Jun 2012 13:28

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