Reaction of keten dithio-acetals with aziridine. Iodide ion-catalysed rearrangement of thio-aziridino-methylene compounds to novel Δ1-2-methylthio-3,3-disubstituted pyrrolines

Kumar, Arvind ; Ila, Hiriyakkanavar ; Junjappa, Hiriyakkanavar ; Mhatre, Sushila (1976) Reaction of keten dithio-acetals with aziridine. Iodide ion-catalysed rearrangement of thio-aziridino-methylene compounds to novel Δ1-2-methylthio-3,3-disubstituted pyrrolines Journal of the Chemical Society - Series Chemical Communications (15). pp. 592-593. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1976...

Related URL: http://dx.doi.org/10.1039/C39760000592

Abstract

The keten dithioacetals (1) and (5) react readily with aziridine (2) to give the corresponding thioaziridinemethylene compounds (3) and (6) respectively, which on iodide ion-catalysed rearrangement, undergo ring expansion to give the pyrrolines (4) and (7) respectively.

Item Type:Article
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