Transition metal-free procedure for the synthesis of S-aryl dithiocarbamates using aryl diazonium fluoroborate in water at room temperature

Chatterjee, Tanmay ; Bhadra, Sukalyan ; Ranu, Brindaban C. (2011) Transition metal-free procedure for the synthesis of S-aryl dithiocarbamates using aryl diazonium fluoroborate in water at room temperature Green Chemistry, 13 (7). pp. 1837-1842. ISSN 1463-9262

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2011...

Related URL: http://dx.doi.org/10.1039/C1GC00001B

Abstract

A convenient, efficient and green procedure for the synthesis of S-aryl dithiocarbamates has been developed by a simple one-pot condensation of aryl diazonium fluoroborate, carbon disulfide and amine in the absence of any transition metal catalyst in water at room temperature. The reactions of a variety of substituted aryl diazonium fluoroborates, and cyclic and open chain amines, have been addressed. The products are purified by crystallization from ethanol and the process does not involve any hazardous solvent.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:92834
Deposited On:05 Jun 2012 10:27
Last Modified:05 Jun 2012 10:27

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