Hydroxyapatite-supported Cu(I)-catalysed cyanation of styrenyl bromides with K4[Fe(CN)6]: an easy access to cinnamonitriles

Saha, Debasree ; Adak, Laksmikanta ; Mukherjee, M. ; Ranu, Brindaban C. (2012) Hydroxyapatite-supported Cu(I)-catalysed cyanation of styrenyl bromides with K4[Fe(CN)6]: an easy access to cinnamonitriles Organic and Biomolecular Chemistry, 10 (5). pp. 952-957. ISSN 1477-0520

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2012...

Related URL: http://dx.doi.org/10.1039/C1OB06467C

Abstract

An efficient cyanation of styrenyl bromides by K4[Fe(CN)6] has been achieved under the catalysis of hydroxyapatite-supported copper(I) producing a variety of functionalized cinnamonitriles in high yields. The stereochemistry of the styrenyl double bond is preserved during the process providing the same stereoisomer of product.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:92831
Deposited On:05 Jun 2012 10:28
Last Modified:05 Jun 2012 10:28

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