Gupta, S. ; Choudhury, R. ; Krois, D. ; Wagner, G. ; Brinker, U. H. ; Ramamurthy, V. (2011) Photochemical generation and reactivity of carbenes within an organic cavitand and capsule: photochemistry of adamantanediazirines Organic Letters, 13 (22). pp. 6074-6077. ISSN 1523-7060
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Official URL: http://pubs.acs.org/journal/orlef7
Abstract
Chemical behavior of carbenes (adamantylidenes) generated by photolysis of adamantanediazirines has been investigated while they were incarcerated within an organic container in water and on silica surfaces. Confined carbenes behave differently from the free ones, and their behavior is dictated by the nature and the structure of the host-guest complexes. The substituent present on the adamantyl skeleton controls the stoichiometry (1:1 or 2:2) and the orientation of guest molecules within the host.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 91582 |
| Deposited On: | 22 May 2012 12:40 |
| Last Modified: | 22 May 2012 12:40 |
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