Ramamurthy, V. ; Corbin, D. R. ; Eaton, D. F. ; Turro, N. J. (1989) Modification of photochemical reactivity by zeolites: Role of cations in controlling the behavior of radicals generated within faujasites Tetrahedron Letters, 30 (43). pp. 5833-5836. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(01)93483-5
Abstract
α-Alkyldibenzylketones included in cation exchanged faujasite type zeolites show photobehavior different from that in isotropic organic solvents. Rearrangement and disproportionation which do not contribute in solution are the major processes within the cavities of faujasites. Cation size plays a major role in controlling the pathway pursued by the primary and the secondary radical pair.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 91451 |
| Deposited On: | 21 May 2012 12:14 |
| Last Modified: | 21 May 2012 12:14 |
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