Ramamurthy, V. ; Corbin, D. R. ; Eaton, D. F. (1989) Modification of photochemical reactivity by zeolites: consequences of rotational restriction on Norrish type II reaction of alkanophenones Journal of the Chemical Society - Series Chemical Communications, 1989 (17). pp. 1213-1214. ISSN 0022-4936
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1989...
Related URL: http://dx.doi.org/10.1039/C39890001213
Abstract
The photolysis of several alkanophenones in monovalent cation exchanged faujasites and in pentasil zeolites, occured with expected γ -hydrogen abstraction and the ratio of the products derived differed; cyclobutanol formation was completely suppressed in pentasils, probably due to restruction of the rotational motion of the central s bond present in the Norrish type II derived 1,4-diradical.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 91450 |
| Deposited On: | 21 May 2012 12:14 |
| Last Modified: | 21 May 2012 12:14 |
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