Studies on aluminum-isopropoxide doped poly(ethylene oxide), poly(vinyl alcohol), and poly(ethylene oxide)-poly(vinyl alcohol) blends

Mishra, Rachna ; Rao, K. J. (1998) Studies on aluminum-isopropoxide doped poly(ethylene oxide), poly(vinyl alcohol), and poly(ethylene oxide)-poly(vinyl alcohol) blends Journal of Applied Polymer Science, 69 (11). pp. 2147-2157. ISSN 0021-8995

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/%28SICI...

Related URL: http://dx.doi.org/10.1002/(SICI)1097-4628(19980912)69:11<2147::AID-APP6>3.0.CO;2-G

Abstract

Poly(ethylene oxide), poly(vinyl alcohol), and their blend in a 40 : 60 mole ratio were doped with aluminum isopropoxide. Their structural, thermal, and electrical properties were studied. Aluminum isopropoxide acts as a Lewis acid and thus significantly influences the electrical properties of the polymers and the blend. It also acts as a scavanger for the trace quantities of water present in them, thereby reducing the magnitude of proton transport. It also affects the structure of polymers that manifests in the thermal transformation and decomposition characteristics.

Item Type:Article
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Deposited On:17 May 2012 04:24
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