Ramaiah, Danaboyina ; Sajimon, Meledathu C. ; Joseph, Joshy ; George, Manapurathu V. (2005) Photoisomerisation of dibenzobarrelenes - a facile route to polycyclic synthons Chemical Society Reviews, 34 (1). pp. 48-57. ISSN 0306-0012
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2005...
Related URL: http://dx.doi.org/10.1039/B300843F
Abstract
Triplet state mediated di-p-methane rearrangements of dibenzobarrelenes give a variety of interesting synthons, formed as primary and secondary photoproducts. These synthons could find use for the synthesis of complex synthetic targets. This tutorial review highlights the photoisomerisation of some bridgehead substituted dibenzobarrelenes and the products derived from them. Selected examples of photoisomerisations proceeding through a tri-π-methane pathway are also included.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 90867 |
| Deposited On: | 14 May 2012 13:59 |
| Last Modified: | 10 Jul 2012 05:59 |
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