Das, Suresh ; Rajesh, C. S. ; Thanulingam, T. L. ; Ramaiah, D. ; George, M. V. (1994) Photochemistry of triethylamine-acid chloride charge-transfer complexes Journal of the Chemical Society, Perkin Transactions 2, 1994 . pp. 1545-1547. ISSN 0300-9580
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/content/articlelanding/1994...
Related URL: http://dx.doi.org/10.1039/P29940001545
Abstract
Charge-transfer (CT) complexes formed between various para-substituted benzoyl chlorides and triethylamine in acetonitrile have been studied spectrophotometrically. Photoactivation of these CT complexes lead to products arising from the reactions of acyl and aminoalkyl radicals. These photochemical processes have been utilized to generate acyl radicals from O-allylsalicylyl chloride which undergoes intramolecular cyclization to form 3-methylchroman-4-one 20 in good yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 90857 |
| Deposited On: | 14 May 2012 13:58 |
| Last Modified: | 10 Jul 2012 05:58 |
Repository Staff Only: item control page
